Benzyl Salicylate

It is used as a solvent for "Synthetic musk & as a Fixative in Floral compositions such as Jasmine, Lilac, Lily etc."

BENZYL SALICYLATE has reported use in the following product types: hair color and bleaching; fragrance for women ; facial moisturizer/treatment; moisturizer; styling gel/lotion ; conditioner; lip gloss; body spray; anti-aging; shampoo.

Benzyl salicylate, also called benzyl 2-hydroxybenzoate, is an almost colorless liquid that comes with a mild balsamic floral scent. This is the reason why you may find this chemical in many soaps, shampoos and fabric softeners. In addition to this, it is a naturally occurring constituent of some type of essential oils like ylang ylang and Cananga oils.

In addition to being used in perfumes, this aromatic chemical is also used in many other products. Some of these products are as follows:

UV light absorber
Hair dyes
Moisturizers
Sunscreen
Bubble bath Cleanser
Aroma Chemicals in Candles

Benzyl Salicylate SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 06-Nov-20

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name & Other Names: Benzyl Salicylate or Benzyl Ortho-Hydroxybenzoate
CAS Number: 118-58-1
EC Code EINECS: 204-262-9
Molecular Formula: 2-(HO)C6H4CO2CH2C6H5
Molecular Weight: 228.24
Relevant uses and uses advised against (if any): Industrial use only.
Supplier: As per letterhead above.

2. HAZARDS IDENTIFICATION

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 2, H315
Sensitization, Skin Category 1, H317
Serious eye damage/eye irritation Category 2A, H319
Hazardous to the aquatic environment, acute hazard Category 2, H401

Labeling according to GHS & Regulation (EC) No 1272/2008

Signal Words: Warning

Hazard Statements:
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H401: Toxic to aquatic life.

Precautionary Statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+352: IF ON SKIN: Wash with soap and water.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P332+313: If skin irritation occurs: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi = Irritant
N = Dangerous for the environment.
Risk Phrases:
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
R51 Toxic to aquatic organisms.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Product Name & Other Names: Benzyl Salicylate or Benzyl Ortho-Hydroxybenzoate
CAS Number: 118-58-1
EC Code EINECS: 204-262-9
FEMA: 2151

4. FIRST-AID MEASURES

Always seek medical advice after the first aid treatment.

Eye Contact: Rinse immediately with plenty of water for 10 minutes at least. Contact a physician if symptoms persist.
Skin Contact: Wash thoroughly with soap and water; flush with plenty of water. Take off spoilt clothes. Contact physician if symptoms persist.
Ingestion: Wash the mouth with water; seek medical advice immediately.
Inhalation: Remove from exposure site to fresh air and keep at rest. Obtain medical advice.

5. FIRE-FIGHTING MEASURES

Extinguishing Media Recommended: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Not Recommended: Do not use direct water jet on burning material.
Extinguishing Procedure: Closed containers may build up pressure at elevated temperatures. If possible, containers should be cooled with a water spray.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

7. HANDLING AND STORAGE

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, acids, alkalis.
Fire Protection: Keep away from ignition sources and naked flame.

8. EXPOSURE CONTROL

Respiratory Precaution: Avoid to breath directly on the product. Apply local ventilations when appropriate.
Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Benzyl Salicylate is colorless / pale-yellow clear liquid/crystalline solid.
Odor: Sweet , Floral , Spicy.
Odor threshold: Not available.
pH: Not available.
Relative density: around 1,176 @ 25C.
Flash Point(C): 180
Boiling Point(C): 335
Melting Point(C): 22 - 24
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Not available.
Viscosity: Not available.
Molecular Formula: 2-(HO)C6H4CO2CH2C6H5
Molecular Weight: 228.24

10. STABILITY AND REACTIVITY

Reactivity: It presents no significant reactivity hazards, by itself or in contact with water. Avoid contact with strong acids, alkalis, or oxidizing agents.
Decomposition: Carbon monoxide and unidentified organic compounds may be formed during combustion.

11. TOXICOLOGICAL INFORMATION

LD 50 ORAL/RAT (mg/Kg): 2227
LD 50 DERMAL/RABBIT (mg/Kg): 14150
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. ECOLOGICAL INFORMATION

Aquatic Toxicity Acute Fish: LC50 Danio rerio 1.03 mg/l, 96 hours
Biodegradability: Degradable.
Precautions: Prevent contamination of soil, ground and surface water
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. DISPOSAL CONSIDERATIONS

In accordance with local environmental laws. Avoid disposing into drainage systems and into the environment.

14. TRANSPORT REGULATIONS

DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
IMDG/IMO & IATA: Not dangerous goods.

15. REGULATORY INFORMATION

USA regulations:
SARA 304 Emergency release notification: Not regulated.
SARA 302 Extremely hazardous substance: Not listed.
SARA 311/312 Hazardous chemical: See section 2.
SARA 313 (TRI reporting): Not regulated.

16. OTHER INFORMATION

European Labeling in Accordance with EC Directives:
H315 = Causes skin irritation.
H317 = May cause an allergic skin reaction.
H319 = Causes serious eye irritation.
H401 = Toxic to aquatic life.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi = Irritant
N = Dangerous for the environment.
Risk Phrases:
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
R51 Toxic to aquatic organisms.