Baccartol

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name & Other Names: Citronellidene Acetone or Baccartol.
CAS Number: 68916-62-1
EINECS Number: 202-938-8
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

2. HAZARDS IDENTIFICATION

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008:

Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Acute toxicity, inhalation Category 4, H332

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements Irritant

Signal Words: Warning

Hazard Statements:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: May be harmful if inhaled.

Precautionary Statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi; Irritant
Risk Phrases:
R36/38: Irritating to eyes and skin.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Product Name & Other Names: Citronellidene Acetone or Baccartol.
CAS Number: 68916-62-1
EINECS Number: 202-938-8

4. FIRST-AID MEASURES

Always seek medical attention after first aid measures are provided.

Eye contact: Rinse immediately with plenty of water for 10 minutes at least. Contact a physician if symptoms persist.
Skin contact: Wash thoroughly with soap and water; flush with plenty of water. Take off spoilt clothes. Contact physician if symptoms persist.
Ingestion: Wash the mouth with water; seek medical advice immediately.
Inhalation: Remove from exposure site to fresh air and keep at rest. Obtain medical advice.

5. FIRE-FIGHTING MEASURES

Extinguishing media recommended: CO2, foam, dry chemicals.
Non-recommended: Do not use direct water jet on burning material.
Extinguishing procedures: In the event of fire, wear self-contained breathing apparatus. Closed containers may build up pressure at elevated temperatures. If possible, containers should be cooled with a water spray. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapors possible in the event of fire.
Products of combustion: Carbon oxides and toxic fumes. If possible, containers should be cooled with a water spray.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Avoid open flames or other sources of ignition.

7. HANDLING AND STORAGE

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and strong acids, alkalis. Heat and light sensitive. Keep away from ignition sources and naked flame.

8. EXPOSURE CONTROL

Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Respiratory Protection: Avoid to breath directly on the product. Apply local ventilations when appropriate.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Citronellidene Acetone is clear colorless to pale yellowish clear mobile liquid.
Odor: Fresh herbal citrus.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: Not available.
Initial boiling point and boiling range: >280C.
Flash point: >100C.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Not available.
Viscosity: Not available.

10. STABILITY AND REACTIVITY

Reactivity: It presents no significant reactivity hazards, by itself or in contact with water. Avoid heat, contact with strong acids, alkalis, or oxidizers.
Decomposition: Carbon monoxide and unidentified organic compounds may be formed.
Hazardous polymerization: Polymerization will not occur.

11. TOXICOLOGICAL INFORMATION

LD 50 ORAL/RAT (mg/Kg) -
LD 50 DERMAL/RABBIT (mg/Kg) -
REMARKS: SKIN IRRITATION: HARD IRRITATING(100mg 24h RABBIT)
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. ECOLOGICAL INFORMATION

Toxicity to fish: No information available.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. DISPOSAL CONSIDERATIONS

In accordance with local environmental laws. Avoid disposing into drainage systems and into the environment.

14. TRANSPORT REGULATIONS

DOT USA, TDG Canada & ADR/RID Europe: Not regulated as dangerous goods.
IMDG/IMO & IATA/ICAO: Not regulated as dangerous goods.

15. REGULATORY INFORMATION

USA:
California Proposition 65: Not listed.
SARA 311/312 Hazards: See section 2.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H332 = May be harmful if inhaled.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi; Irritant
Risk Phrases:
R36/38: Irritating to eyes and skin.