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Formic Acid Analytical Reagent

CAS No.: 64-18-6
Molecular Weight: 46.03 g/mol
Chemical Formula CH2O2

Formic acid or Methanoic acid is the simplest carboxylic acid. It is an important intermediate in chemical synthesis and occurs naturally, most notably in some ants. Formic acid is a colorless liquid having a pungent, penetrating odor at room temperature.

General Properties & Specifications of Formic acid or Methanoic acid:
CAS number: 64-18-6
Chemical formula: CH2O2
Molecular weight: 46.03
Appearance
: Colorless fuming liquid.
Odor: Pungent, penetrating.
Relative Density: 1.22
Melting point: 8C literature.
Boiling point: 101C literature.
Flash point: 50C literature. (Lowest of the reported).
Auto-ignition temperature: >500C literature.
Boiling point: 101C literature.
Decomposition temperature: 350 C.
Solubility in water: Miscible
Solubility: Miscible with ether, acetone, ethyl acetate, glycerol, methanol, ethanol. Partially soluble in benzene, toluene, xylenes.


Formic Acid FCC Food Grade:
HCOOH
CH2O2 Formula wt 46.03
INS: 236 CAS: [64-18-6]
FEMA: 2487
DESCRIPTION
Formic Acid occurs as a clear, colorless, highly corrosive liquid with a characteristic, pungent odor. It is miscible with water, with alcohol, with glycerin, and with ether. Its specific gravity is about 1.20.
Function: Flavoring adjunct; preservative.
REQUIREMENTS
Identification:
A. Add 2 mL of mercuric chloride to 5 mL of sample, and warm the mixture. A white precipitate of mercurous chloride forms.
B. Neutralize 1 mL of sample with sodium hydroxide, and then add 2 drops in excess and 1 mL of ferric chloride. A deep, red-orange color appears that turns to yellow-orange on the addition of mineral acids.
C. Place 2 mL of sample in a test tube, add 5 mL of sulfuric acid, and test the gas evolved with a lighted splinter. A blue flame characteristic of carbon monoxide is produced.
Assay: Not less than 85.0% of CH2O2.
Acetic Acid: Not more than 0.4%.
Dilution Test: Passes test.
Sulfate: Not more than 0.004%.


Formic Acid, 96% Analytical Reagent Grade:
HCOOH --- Formula Wt 46.03 --- CAS Number 64-18-6
CAUTION: Slow decomposition of this reagent may produce pressure in the bottle. Loosen cap occasionally to vent the gas.
REQUIREMENTS
Assay: 96.0% HCOOH
MAXIMUM ALLOWABLE
Color (APHA): 15
Dilution test: Passes test
Residue after evaporation: 0.003%
Acetic acid (CH3COOH): 0.4%
Ammonium (NH4): 0.005%
Chloride (Cl): 0.001%
Sulfate (SO4): 0.003%
Sulfite (SO3): Passes test
Heavy metals (as Pb): 0.001%
Iron (Fe): 0.001%.


Formic Acid, 88% Analytical Reagent Grade:
HCOOH --- Formula Wt 46.03 --- CAS Number 64-18-6
REQUIREMENTS
Assay: 88.0% HCOOH

MAXIMUM ALLOWABLE
Color (APHA): 15
Dilution test: Passes test
Residue after evaporation: 0.002%
Acetic acid (CH3COOH): 0.4%
Ammonium (NH4): 0.005%
Chloride (Cl) 0.001%
Sulfate (SO4): 0.002%
Sulfite (SO3): Passes test
Heavy metals (as Pb): 5 ppm
Iron (Fe): 5 ppm.